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Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

Pre-chamber combustion (PCC) enables leaner air-fuel ratio operation by improving its ignitability and extending flammability limit, and consequently, offers better thermal efficiency than conventional spark ignition operation. The geometry and fuel concentration of the pre-chamber (PC) is one of the major parameters that affect overall performance. To understand the dynamics of the PCC in practical engine conditions, this study focused on (i) correlation of the events in the main chamber (MC) with the measured in-cylinder pressure traces and, (ii) the effect of fuel concentration on the MC combustion characteristics using laser diagnostics. We performed simultaneous acetone planar laser-induced fluorescence (PLIF) from the side, and OH* chemiluminescence imaging from the bottom in a heavy-duty optical engine. Two different PC Fueling Ratios (PCFR, the ratio of PC fuel to the total fuel), 7%, and 13%, were investigated.

The aim of this study is to see how geometry generated turbulence affects the Rate of Heat Release (ROHR) in an HCCI engine. HCCI combustion is limited in load due to high peak pressures and too fast combustion. If the speed of combustion can be decreased the load range can be extended. Therefore two different combustion chamber geometries were investigated, one with a disc shape and one with a square bowl in piston. The later one provokes squish-generated gas flow into the bowl causing turbulence. The disc shaped combustion chamber was used as a reference case. Combustion duration and ROHR were studied using heat release analysis. A Scania D12 Diesel engine, converted to port injected HCCI with ethanol was used for the experiments. An engine speed of 1200 rpm was applied throughout the tests. The effect of air/fuel ratio and combustion phasing was also studied.

In this work the pre- to main chamber ignition process is studied in a Wärtsilä 34SG spark-ignited lean burn four-stroke large bore optical engine (bore 340 mm) operating on natural gas. Unburnt and burnt gas regions in planar cross-sections of the combustion chamber are identified by means of planar laser induced fluorescence (PLIF) from acetone seeded to the fuel. The emerging jets from the pre-chamber, the ignition process and early flame propagation are studied. Measurements reveal the presence of a significant temporal delay between the occurrence of a pressure difference across the pre-chamber holes and the appearance of hot burnt/burning gases at the nozzle exit. Variations in the delay affect the combustion timing and duration. The combustion rate in the pre-chamber does not influence the jet propagation speed, although it still has an effect on the overall combustion duration.

A diesel engine developed for an international market must be able to run on different fuels considering the diesel fuel qualities and the increasing selection of biofuels in the world. This leads to the question of how different fuels perform relative to a standard diesel fuel when not changing the hardware settings. In this study five fuels (Japanese diesel, MK3, EN590 with 10% RME, EN590 with 30% RME and pure RME) have been compared to a reference diesel fuel (Swedish MK1) when run on three different speeds and three different loads at each speed. The experiments are run on a Scania 13l Euro5 engine with standard settings for Swedish MK1 diesel. In general the differences were not large between the fuels. NO x usually increased compared to MK1 and then soot decreased as would be expected. The combustion efficiency increased with increased RME contents of the fuel but the indicated efficiency was not influenced by RME except for at higher loads.

An engine can be run in Homogenous Charge Compression Ignition (HCCI) mode by applying a negative valve overlap, thus trapping hot residuals so as to achieve an auto-ignition temperature. By employing spark assistance, the engine can be operated in what is here called Spark Assisted Compression Ignition (SACI) with ethanol as fuel. The influence of fuel stratification by means of port fuel injection as well as in combination with direct injection was investigated. A high-speed multi-YAG laser system and a framing camera were utilized to capture planar laser-induced fluorescence (PLIF) images of the fuel distribution. The charge homogeneity in terms of fuel distribution was evaluated using a homogeneity index calculated from the PLIF images. The homogeneity index showed a higher stratification for increased proportions of direct-injected fuel. It was found that charge stratification could be achieved through port fuel injection in a swirling combustion system.

Partially premixed combustion (PPC) is a low-temperature combustion concept that could deliver higher engine efficiency, as well as lower emissions. Gasoline-like fuel compression ignition (GCI) is beneficial for air/fuel mixing process under PPC mode because of the superior auto-ignition resistance to prolong ignition delay time. In current experiments, three surrogate fuels with same research octane number (RON77) but different octane sensitivities (OS), PRF77 (S = 0), TPRF77-a (S = 3) and TPRF77-b (S = 5), are tested in a full-transparent single cylinder AVL optical compression ignition (CI) engine at low load conditions. Aiming at investigating the fuel octane sensitivity effect on engine combustion behavior as well as emissions under GCI-PPC mode, engine parameters, and emission data during combustion are compared for the test fuels with a change of injection timing.

Homogeneous Charge Compression Ignition (HCCI) has a great potential for low NOx emissions but problems with emissions of unburned hydrocarbons (HC). One way of reducing the HC is to use direct injection. The purpose of this paper is to present experimental data on the trade off between NOx and HC. Injection timing, injection pressure and nozzle configuration all effect homogeneity of the mixture and thus the NOx and HC emissions. The engine studied is a single cylinder version of a Scania D12 that represents a modern heavy-duty truck size engine. A common rail (CR) system has been used to control injection pressure and timing. The combustion using injectors with different nozzle hole diameters and spray angle, both colliding and non-colliding, has been studied. The NOx emission level changes with start of injection (SOI) and the levels are low for early injection timing, increasing with retarded SOI. Different injectors produce different NOx levels.

Spray and combustion of gasoline and diesel were visualized under different ambient conditions in terms of pressure, temperature and density in a constant volume chamber. Three different ambient conditions were selected to simulate the three combustion regimes of homogeneous charge compression ignition, premixed charge compression ignition and conventional combustion. Ambient density was varied from 3.74 to 23.39 kg/m3. Ambient temperature at the spray injection were controlled to the range from 474 to 925 K. Intake oxygen concentration was also modulated from 15 % to 21 % in order to investigate the effects of intake oxygen concentrations on combustion characteristics. The injection pressure of gasoline and diesel were modulated from 50 to 150 MPa to analyze the effect of injection pressure on the spray development and combustion characteristics. Liquid penetration length and vapor penetration length were measured based on the methods of Mie-scattering and Schileren, respectively.

Previous work has shown that it may be advantageous to use gasoline type fuels with long ignition delays compared to today's diesel fuels in compression ignition engines. In the present work we investigate if high volatility is also needed along with low cetane (high octane) to get more premixed combustion leading to low NO and smoke. A single-cylinder light-duty compression ignition engine is run on four fuels in the diesel boiling range and three fuels in the gasoline boiling range. The lowest cetane diesel boiling range fuel (DCN = 22) also has very high aromatic content (75%vol) but the engine can be run on this to give very low NO (≺ 0.4 g/kWh) and smoke (FSN ≺ 0.1), e.g,. at 4 bar and 10 bar IMEP at 2000 RPM like the gasoline fuels but unlike the diesel fuels with DCNs of 40 and 56. If the combustion phasing and delay are matched for any two fuels at a given operating condition, their emissions behavior is also matched regardless of the differences in volatility and composition.

Small bore diesel engines often adopt a two-valve cylinder head and a non-central injector layout to expand the port flow passage area. This non-central injector layout causes asymmetrical gas flow and fuel distribution, resulting in worse heat losses and a less homogenous fuel-air mixture than an equivalent four-valve cylinder head layout with a central injector. This paper describes the improvement of piston bowl geometry to achieve a more homogeneous gas flow and fuel-air mixture. This concept reduced fuel consumption by 2.5% compared to the original piston bowl geometry, while also reducing NOx emissions by 10%.

Simultaneous laser induced fluorescence (LIF) imaging of formaldehyde and a fuel-tracer have been performed in a direct-injection HCCI engine. A mix of N-heptane and iso-octane was used as fuel and Toluene as fluorescent tracer. The experimental setup involves two pulsed Nd:YAG lasers and two ICCD cameras. Frequency quadrupled laser radiation at 266 nm from one of the Nd:YAG lasers was used for excitation of the fuel tracer. The resulting fluorescence was detected with one of the ICCD cameras in the spectral region 270-320 nm. The second laser system provided frequency tripled radiation at 355 nm for excitation of Formaldehyde. Detection in the range 395-500 nm was achieved with the second ICCD. The aim of the presented work is to investigate the applicability of utilizing formaldehyde as a naturally occurring fuel marker. Formaldehyde is formed in the low temperature reactions (LTR) prior to the main combustion and should thus be present were fuel is located until it is consumed.

Simultaneous OH- and formaldehyde LIF measurements have been performed in an HCCI engine using two laser sources working on 283 and 355 nm, respectively. Two ICCD camera systems, equipped with long-pass filters, were used to collect the LIF signals. The simultaneous images of OH and formaldehyde were compared with heat-release calculated from the pressure-trace matching the cycle for the LIF measurements. The measurements were performed on a 0.5 l single-cylinder optical engine equipped with port-fuel injection system. A blend of iso-octane and n-heptane was used as fuel and the compression ratio was set to 12:1. The width of the laser sheet was 40 mm and hence covered approximately half of the cylinder bore. At some 20 CAD BTDC low temperature reactions is present and formaldehyde is formed. The formaldehyde signal is then rather constant until the main heat-release starts just before TDC, where the signal decreases rapidly to low values.

Pre-chamber combustion (PCC) is a promising engine combustion concept capable of extending the lean limit at part load. The engine experiments in the literature showed that the PCC could achieve higher engine thermal efficiency and much lower NOx emission than the spark-ignition engine. Improved understanding of the detailed flow and combustion physics of PCC is important for optimizing the PCC combustion. In this study, we investigated the gas exchange and flame jet from a narrow throat pre-chamber (PC) by only fueling the PC with methane in an optical engine. Simultaneous negative acetone planar laser-induced fluorescence (PLIF) imaging and OH* chemiluminescence imaging were applied to visualize the PC jet and flame jet from the PC, respectively. Results indicate a delay of the PC gas exchange relative to the built-up of the pressure difference (△ P) between PC and the main chamber (MC). This should be due to the gas inertia inside the PC and the resistance of the PC nozzle.

Simultaneous laser-induced fluorescence (LIF) imaging of formaldehyde and a fuel-tracer have been performed in a high-speed diesel engine. N-heptane and isooctane were used as fuel and toluene was used as a tracer. This arrangement made it possible to make simultaneous measurements of toluene by exciting at 266 nm and detecting at 270-320 nm while exciting formaldehyde at 355 nm and detecting at 400-500 nm. The aim of this study is to investigate how traditional fuel tracer and natural-occurring formaldehyde formed in the cool chemistry are transported in the piston bowl. A range of ignition delays were created by running the engine with different amounts of EGR. During this sweep the area where the low-temperature reactions take place were studied. The measurements were performed in a 0.5-l, single-cylinder optical engine running under conditions simulating a cruise-point, i.e., about 2.2 bar imep.

In the study presented in this paper, experimental data from a pneumatic hybrid has been compared to the results from a simulation of the engine in GT-Power. The engine in question is a single-cylinder Scania D12 diesel engine, which has been converted to work as a pneumatic hybrid. The base engine model, provided by Scania, is made in GT-Power and it is based on the same engine configuration as the one used during real engine testing. During pneumatic hybrid operation the engine can be used as a 2-stroke compressor for generation of compressed air during vehicle deceleration and during vehicle acceleration the engine can be operated as a 2-stroke air-motor driven by the previously stored pressurized air. There is also a possibility to use the stored pressurized air in order to supercharge the engine when there is a need for high torque, like for instance at take off after a standstill or during an overtake maneuver.

This paper focuses on the performance and efficiency of an HCCI (Homogenous Charge Compression Ignition) engine system running on natural gas or landfill gas for stationary applications. Zero dimensional modeling and simulation of the engine, turbo, inlet and exhaust manifolds and inlet air conditioner (intercooler/heater) are used to study the effect of compression ratio and exhaust turbine size on maximum mean effective pressure and efficiency. The extended Zeldovich mechanism is used to estimate NO-formation in order to determine operation limits. Detailed chemical kinetics is used to predict ignition timing. Simulation of the in-cylinder process gives a minimum λ-value of 2.4 for natural gas, regardless of compression ratio. This is restricted by the NO formation for richer mixtures. Lower compression ratios allow higher inlet pressure and hence higher load, but it also reduces indicated efficiency.

The blending of ethanol with primary reference fuel (PRF) mixtures comprising n-heptane and iso-octane is known to exhibit a non-linear octane response; however, the underlying chemistry and intermolecular interactions are poorly understood. Well-designed experiments and numerical simulations are required to understand these blending effects and the chemical kinetic phenomenon responsible for them. To this end, HCCI engine experiments were previously performed at four different conditions of intake temperature and engine speed for various PRF/ethanol mixtures. Transfer functions were developed in the HCCI engine to relate PRF mixture composition to autoignition tendency at various compression ratios. The HCCI blending octane number (BON) was determined for mixtures of 2-20 vol % ethanol with PRF70. In the present work, the experimental conditions were considered to perform zero-dimensional HCCI engine simulations with detailed chemical kinetics for ethanol/PRF blends.

This paper compares the greenhouse gas (GHG) emissions attributed to driving a popular production vehicle powered by an internal combustion engine (ICE), as well as a hybrid electric vehicle (HEV), with GHG emissions associated with walking, running and bicycling. The purpose of this study is to offer a different perspective on the problem of global warming due to anthropogenic causes, specifically on transportation and eating patterns. In order to accurately estimate emissions, a full life cycle of food has been considered coupled with energy expenditures of the aforementioned activities obtained from several different sources and averaged for more reliable results. The GHG emissions were calculated for Sweden, the UK, and the US. Depending on the availability of certain data, the methodology for different countries was altered slightly. The question whether walking, running or taking a bicycle is better for the environment than driving a car cannot be answered uniquely.

Partially Premixed Combustion (PPC) is a promising advanced combustion mode for future engines. In order to investigate the sensitivity of PPC to exhaust gas recirculation (EGR) rate, intake gas temperature, intake gas pressure, and injection timing, these parameters were swept individually at three different loads in a single cylinder diesel engine with gasoline-like fuel. A factor of sensitivity was defined to indicate the combustion's controllability and sensitivity to inlet gas parameters and injection timings. Through analysis of experimental results, a control window of inlet gas parameters and injection timings is obtained at different loads in PPC mode from 5 bar to 10 bar IMEPg load at 1200 rpm. To further study the PPC controllability with injection timing, main injection timing was adjusted to sustain steady combustion phasing subject to perturbation of inlet gas state.